The most number of orgasms I have ever had in a single masturbation session was about 140. It was not in a single hour though, more like 2 hours. I did not use a toy. The reason I know how many it was, was because I was reading a book, and I gave myself an orgasm for every second page I read. By the end of it, my legs had cramped a LOT. But it was awesome.
I find that I can bring myself to orgasm within a minute, if I'm really motivated, and once I've orgasmed once, I can orgasm again within about 30-40 seconds, and continue on depending on how much energy I have to keep going. Now I usually stop after 2 or 3 orgasms, but sometimes go to about 10. My record was when I was a teenager who had recently discovered masturbation so was addicted to how good it felt.